Leaching Kinetics of Hemimorphite with 5-Sulfosalicylic Acid
نویسندگان
چکیده
The kinetics of leaching zinc from hemimorphite was investigated. factors that influence were also evaluated, and a kinetic model built. In addition, scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS) used to investigate the changes surface morphology before after leaching. By decreasing particle size increasing temperature, 5-sulfosalicylic acid concentration, stirring speed, rate can be enhanced. shrinkage nucleus describes chemistry activation energy by in process determined as 55.244 kJ/mol. reaction based on expressed semi-empirical formula:1−1−x1/3 =[k0C0.3385(r0)−0.6083(SS)0.4992exp(−55.244/RT)]t. At condition 50 °C 0.175 mol/L 82.5 μm 650 rpm high rates obtained. After time 15 min, reached more than 95%. According SEM-EDS results, residue are distributed blocks, but is smaller, atomic concentrations Zn Si significantly lower those hemimorphite, so effect remarkable. Therefore, solution would an excellent agent for extraction hemimorphite.
منابع مشابه
Kinetics of Sphalerite Leaching by Sodium Nitrate in Sulfuric Acid
In the present work, the extraction of zinc from a sphalerite concentrate using sodium nitrate as an oxidant in a sulfuric acid solution was investigated. The effective parameters such as the temperature, sulfuric acid and sodium nitrite concentrations, stirring speed, particle size, and solid/liquid (S/L) ratio were analyzed. The dissolution rate increased with increase in the sulfuric acid an...
متن کاملInvestigation of Leaching Kinetics of Smithsonite Ore
The leaching kinetics of smithsonite ore in acetic acid solutions, an environmental friend, and natural reagent was investigated. The influence of parameters such as reaction temperature, particle size, solid-liquid ratio and acid concentration was studied in order to reveal the leaching kinetics of smithsonite ore. In this study, experimental and statistical methods were carried out in order t...
متن کاملHydrogen bonding in proton-transfer compounds of 5-sulfosalicylic acid with bicyclic heteroaromatic Lewis bases.
The crystal structures of quinolinium 3-carboxy-4-hydroxybenzenesulfonate trihydrate, C9H8N + C7H5O6S 3H2O, (I), 8-hydroxyquinolinium 3-carboxy-4-hydroxybenzenesulfonate monohydrate, C9H8NO + C7H5O6S H2O, (II), 8-aminoquinolinium 3-carboxy-4-hydroxybenzenesulfonate dihydrate, C9H9N2 + C7H5O6S 2H2O, (III), and 2-carboxyquinolinium 3-carboxy-4-hydroxybenzenesulfonate quinolinium-2-carboxylate, C1...
متن کاملKinetics of Sphalerite leaching by Sodium Nitrate in Sulfuric Acid
In the present work, the extraction of zinc from a sphalerite concentrate using sodium nitrate as an oxidant in a sulfuric acid solution was investigated. The effective parameters such as the temperature, sulfuric acid and sodium nitrite concentrations, stirring speed, particle size, and solid/liquid (S/L) ratio were analyzed. The dissolution rate increased with increase in the sulfuric acid an...
متن کامل5-sulfosalicylic acid as an efficient organocatalyst for environmentally benign synthesis of 2-substituted benzimidazoles
A water soluble, Bronsted acid, 5-sulfosalicylic acid as an efficient organocatalyst was used for the synthesis of physiologically active 2-substituted benzimidazole derivatives from o-phenylenediamine and aromatic aldehydes in ethanol at reflux condition. Cost-effectiveness, use of non-hazardous solvents, metal free and commercially available catalyst, single-step, environmentally fri...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Metals
سال: 2023
ISSN: ['2075-4701']
DOI: https://doi.org/10.3390/met13071249